Hey there,
You can adjust the meter whenever you feel somethings off. I agree with the rest, that a known water PH is one very effective way of making sure the calibration is correct. Always keep your meter in a storage solution. Most pens have a reservoir built into the cap. I have three bottles of calibration solution. One is 4.0, one at 7.0 and 10.0. Keep everything in a warm environment not a cold basement, even your water. Trying to PH anything in a cool environment will give you false readings, unless your pen has a built in temperature adjustment sensor. PH water adjustment should always be done at a temperature between 75 and 80 degrees. Never shake your water mixture as this will give you an unrealistic value. Gently swish the nutrient and water mixture for accuracy.
PH is very crucial for healthy plant development, so even if you calibrate every time it's not too much.
Hope this helps,
The Nerd