Hygrometers (humidity measuring devices, including the one installed in your dehumidifier) are notoriously inaccurate. I see about 46% on your standalone hygrometer and 39% on your dehumidifier, that’s honestly not too bad of a difference. If you want to measure with better accuracy than that, I recommend something like a Sensor Push, or similar device, and even then you’ll want to calibrate both the temperature and the humidity readings. You can buy 75.5% calibration packs from Boveda and put the sensor push in a sealed container with the pack and watch where the readings settle, then program in a calibration offset compared to 75.5%. That’s how you know whether or not your measurement is accurate.