Light hanging distance (specifically with LED) can cause crazy colors like that. I had a QB too close to some saplings and saw purple coloration as well one time.
when you say PH has been good, what does that mean? What was the PH of the water going in, and the run off coming out? Takes the guesswork out of the equation.
lastly, rain water could be the problem in itself. Depending on how you sourced it. If it came from a roof/gutter system and was collected this way... there could be a whole lot of issues with ph, pathogens, and what ever else was collected with it. Potentially that could be your issue besides the other possibilities I mentioned.