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Sulfured molasses will increase acidity but unsulfured shouldn't affect PH. I use it throughout my grows, not just during flower. The use of molasses is not intended as a nutrient for plants but rather to feed the microbes that help break down soil nutrients to be more readily available for absorption. I begin building my soil months prior to planting and use molasses during that process as well because the beneficial microbes it feeds are very efficient at balancing PH levels.
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